The Journal of Organic Chemistry

Polychlorinated ketones. III. Formation by acid-catalyzed cleavage of vinyl phosphates and phosphonates

K Pilgram, F Goergen, H Ohse

文献索引：Pilgram,K. et al. Journal of Organic Chemistry, 1969 , vol. 34, p. 3558 - 3561

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被引用次数: 1

摘要

Reaction product was not analyzed; distillation was attempted but decomposition occurred. tivity, primary< secondary, clearly is that which would be anticipated for a reaction involving a carbonium-ion intermediate (El). This is also most certainly the route by which acid- catalyzed dehydrations of most alcohols proceed. lo Initial protonation (El reaction) may be envisaged to involve the phosphoryl-oxygen atom (Va) or the oxygen atom of the alkoxy ...