Dewar furan and Dewar thiophene: low-temperature matrix photolysis of furan and thiophene

WA Rendall, A Clement, M Torres…

文献索引：Rendall, W. A.; Clement, A.; Torres, M.; Strausz, O. P. Journal of the American Chemical Society, 1986 , vol. 108, # 7 p. 1691 - 1692

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被引用次数: 23

摘要

Earlier we reported2 the formation of Dewar thiophene (1) in the room-tempeature liquid- phase photolysis of thiophene (2), by its trapping as Diels-Alder adducts with furan (3). The analogous liquid-phase photolysis of furan, on the other hand, yielded furan Diels-Alder adducts with 2, 3-butadienal (4) and cyclopropene-3-carbaldehyde (5) but not with Dewar furan (6). 3 In an effort to gain further insight into the chemistry of these Dewar ...