Tetrahedron Letters

Homolysis of the TL-C bond in hydrodethallation of alkylthallium (III) compounds with n-benzyl-1, 4-dihydronicotinamide

H Kurosawa, H Okada, M Yasuda

文献索引：Kurosawa, Hideo; Okada, Hiroshi; Yasuda, Masahide Tetrahedron Letters, 1980 , vol. 21, p. 959 - 960

全文：HTML全文

被引用次数: 12

摘要

Abstract Reduction of alkylthallium (III) compounds, RT1X 2 with N-benzyl-1, 4- dihydronicotinamide to give high yields of RH compounds proceeds through homolysis of the Tl-C bond of an alkylthallium (II) intermediate formed by one-electron reduction of RT1X 2.