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New Reactions Involving Alkaline Treatment of 3-Nitroso-2-oxazolidones1

MS Newman, A Kutner

文献索引:Newman; Kutner Journal of the American Chemical Society, 1951 , vol. 73, p. 4199,4202

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被引用次数: 78

摘要

CHt-NN= O described. and vinyl ethers. When the R groups are aliphatic, aldehydes, RR'CHCHO, are formed. method for going from RCOR'to RR'CHCHO. general method for going from ArCOAr to A rb CA r is at hand although its generality is yet to be established. R is aliphatic and one is phenyl, a mixture of disubstituted acetylene and ketone is obtained. tion is carried out in absolute alcohols, vinyl ethers are obtained. bonium ion, RR'C= C+ H, ...