Journal of organometallic chemistry

Oxidation of olefins by palladium (II). 18. Effect of reaction conditions, substrate structure and chiral ligand on the bimetallic palladium (II) catalyzed asymmetric …

AK El-Qisairi, HA Qaseer, PM Henry

文献索引：El-Qisairi, Arab K; Qaseer, Hanan A; Henry, Patrick M Journal of Organometallic Chemistry, 2002 , vol. 656, # 1-2 p. 168 - 176

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被引用次数: 35

摘要

The effect of electronic factors, solvent composition, identity of the chiral bidentate, and olefin structure on the yields and enantioselectivities of the asymmetric chlorohydrin synthesis were investigated. Electronic effects on the chlorohydrin reaction were tested by oxidation of phenyl allyl ether p-substituted by H, Cl, CH3O and CN. All species gave same similar yields and enantioselectivities indicating that electronic effects are not important. Varying the ...