Tetrahedron

Synthesis and structural studies of some gold (I) complexes containing selenoureato ligands

A Molter, J Rust, CW Lehmann, F Mohr

文献索引：Molter, Anja; Mohr, Fabian; Rust, Joerg; Lehmann, Christian W. Tetrahedron, 2012 , vol. 68, # 51 p. 10586 - 10591,6

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被引用次数: 10

摘要

N, N-Diethyl-N′-4-nitrobenzoylselenourea (HLSe) reacts with the mono-and dinuclear phosphine gold (I) chloro complexes [AuCl (PR3)](R= Ph, o-tol, Et) and [Au2Cl2 (μ-PP)](PP= dppm, dppe, dppp, dppb, dppf) in the presence of base to give gold (I) phosphine selenoureato complexes [Au (LSe)(PR3)][R= Ph (1), o-tol (2), Et (3)],[Au2 (LSe) 2 (μ- PP)][PP= dppm (4), dppe (5), dppp (6), dppb (7), dppf (8)] in excellent yields. The ...