Journal of organometallic chemistry

Photochemistry of aryl-substituted trigermanes. Generation and mechanism of formation of germylenes

K Mochida, I Yoneda, M Wakasa

文献索引：Mochida, Kunio; Yoneda, Isao; Wakasa, Masanobu Journal of Organometallic Chemistry, 1990 , vol. 399, # 1/2 p. 53 - 62

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被引用次数: 41

摘要

Abstract Photochemical reactions of aryl-substituted trigermanes have studied by trapping experiments, matrix isolation, and laser flash-photolysis techniques. Photolysis of the phenylated trigermanes involved both the simple extrusion of germylenes and the formation of germyl radicals and digermyl radicals. The photochemically generated germylenes react with 2, 3-dimethylbutadiene or CCl 4 to give germacyclopentenes or ...