The Journal of Organic Chemistry

Hydroformylation of bisolefinic amine derivatives catalyzed by cobalt and rhodium

ME Garst, D Lukton

文献索引：Garst, Michael E.; Lukton, David Journal of Organic Chemistry, 1981 , vol. 46, # 22 p. 4433 - 4438

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被引用次数: 46

摘要

Three bisolefic carbamates and five N, N-diallyl N-substituted amines have been subjected to hydroformylation conditions under catalysis by HCO (CO)~, CO (CO)~, and (Ph, P), Rh (H) CO in an attempt to prepare heterocyclic ketones. The products differ with amines and carbamates and with the catalyst. Carbamate 3 and HCO (CO)~ gave 3-pyrrolidinone (4) in 45% yield. The cobalt-catalyzed reaction of 8 and rhodium-catalyzed reaction of 3 and of 8 ...