Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions

AI Ilovaisky, VM Merkulova, YN Ogibin…

文献索引：Ilovaisky; Merkulova; Ogibin; Nikishin Russian Chemical Bulletin, 2005 , vol. 54, # 7 p. 1585 - 1592

被引用次数: 3

摘要

Abstract Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1-and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH 2 Cl 2/H 2 O) produces geminal nitrohalides (35–85% yields), dinitro compounds (15–51%), nitronitriles (6–27%), and ...

~53%

~12%

3964-18-9

2,3-二甲基-2,3-二硝基丁烷

~4%

~53%

~67%

~49%

~27%

详细

~20%

详细

~67%

~21%

~9%

~25%

~25%

详细

~34%

~43%

~9%

~1%

. alpha.-Nitro sulfones. 2. Convenient new synthesis and sel...

[Wade, Peter A.; Hinney, Harry R.; Amin, Nayan V.; Vail, Peter D.; Morrow, Scott D.; et al. Journal of Organic Chemistry, 1981 , vol. 46, p. 765 - 770]

C-alkylation reactions of phenylsulphonylnitromethane. A con...

[Wade, Peter A.; Morrow, Scott D.; Hardinger, Steven A.; Saft, Mallory S.; Hinney, Harry R. Journal of the Chemical Society, Chemical Communications, 1980 , # 6 p. 287 - 288]