Highly efficient synthesis of diethyl carbonate via one-pot reaction from carbon dioxide, epoxides and ethanol over KI-based binary catalyst system

L Wang, H Li, S Xin, P He, Y Cao, F Li, X Hou

文献索引：Wang, Liguo; Li, Huiquan; Xin, Shumin; He, Peng; Cao, Yan; Li, Fengjiao; Hou, Xinjuan Applied Catalysis A: General, 2014 , vol. 471, p. 19 - 27

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被引用次数: 10

摘要

Abstract The synthesis of diethyl carbonate (DEC) directly from carbon dioxide, ethylene oxide (EO), and ethanol via one-pot reaction is reported for the first time. The effects of catalyst species and reaction variables on the synthetic performance of DEC were systematically studied. The integration of easily available KI and sodium ethoxide as homogeneous binary catalyst system was found to be very active for the one-pot reaction, ...