Direct carbonylation of polychloroalkanes into acid chlorides using metallic salts ternary systems: an example of multistep catalysis

E Monflier, A Mortreux, F Petit, S Lécolier

文献索引：Monflier, Eric; Mortreux, Andre; Petit, Francis; Lecolier, Serge Journal of the Chemical Society, Chemical Communications, 1992 , # 5 p. 439 - 441

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摘要

Polychloroalkanes arc of interest as industrial intermediates but suffcr from relative chemical inertness. Direct carbonyl- ation of polychloroalkanes into acid chlorides has previously been reported and this reaction requires harsh conditions: a high pressure of carbon monoxide (900 bar)' or medium pressure (300 bar) using metal carbonyls such as Fe(CO)5." Consequently, direct carbonylation still remains a real chal- lenge. We report here that the carbonylation ...