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Chemistry Letters

Perfluoroalkylation of aromatic compounds with R f I (Ph) OSO 2 CF 3

T Umemoto, Y Kuriu, H Shuyama

文献索引:Umemoto, Teruo; Kuriu, Yuriko; Shuyama, Hideo Chemistry Letters, 1981 , p. 1663 - 1666

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被引用次数: 38

摘要

Chemistry Letters, 19 8 1 1665 the same ones in rather good yields (Run 20 and 21 in Table 1). On the other hand, the reaction with тг -electron-deficient aromatic compounds such as methyl benzoate occurred in acetonitrile at 82°C in the presence of pyridine. Similarly to FITS, perfluoroalkylphenyliodonium sulfate (FIS)D^ reacted with various aromatic compounds to give the products (Scheme 2). The results and re- action conditions are shown in Table 2, As a whole, the reactivity of FIS is ...