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Canadian Journal of Chemistry

Betylates. 1. Synthesis and reactions of an isolable [0] betylate, N, N-dimethyl-N-(phenoxysulfonyl) methanaminium fluorosulfate

JF King, TML Lee

文献索引:King, James Frederick; Lee, Teresa Mee-Ling Canadian Journal of Chemistry, 1981 , vol. 59, p. 356 - 361

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被引用次数: 8

摘要

Phenyl [0] betylate fluorosulfate (2), the first example of a"[0] betylate"(trialkylammoniosulfate ester), has been prepared by methylation of phenyl N, N-dimethylsulfamate with methyl fluorosulfate. Nucleophiles react with 2 either by attack on the sulfur or methyl carbon atoms,