Inorganic chemistry

Kinetic Studies of the reactions of pentacyanoferrate (ii) complexes with peroxydisulfate

MH Chen, S Lee, S Liu, A Yeh

文献索引：Chen, Ming Hung; Lee, Sheena; Liu, Scott; Yeh, Andrew Inorganic Chemistry, 1996 , vol. 35, # 9 p. 2627 - 2629

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被引用次数: 33

摘要

Reactions of a series of Fe (CN) 5L3-complexes with peroxydisulfate have been found to follow an outer-sphere electron transfer mechanism. The specific rate constants of oxidation are smaller than those of the corresponding Ru (NH3) 5L2+ complexes by a factor of~ 102 even after the corrections for the differences in reduction potentials and in the charges of the complexes. Hydrogen bonding between peroxydisulfate and the ammonia ligands of Ru ( ...