Polyhedron

Isolation of [Rh (diolefin) X2]-species and their reactions with P-or N-donor ligands, tin (II) halides and carbon monoxide

MA Garcia, MA Garralda, L Ibarlucea

文献索引：Garcia, M. A.; Garralda, M. A.; Ibarlucea, L. Polyhedron, 1988 , vol. 7, p. 1067 - 1070

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被引用次数: 8

摘要

Abstract Anionic [Rh (diolefin) X 2]− species (X= Cl, Br) have been prepared and their reactions studied. The reactions with monodentate ligands led to neutral tetracoordinated complexes, and with N-donor bidentate ligands (Rh: LL= 2: 1) gave Rh (X)(diolefin)(LL),[Rh (diolefin)(LL)]+[Rh (diolefin) X 2]−, or [Rh (diolefin)(LL)] X compounds, depending on the nature of LL or X. Reactions with carbon monoxide involved diolefin displacement. A ...