The process of 4??hydroxybiphenyl synthesis from 4??isopropylbiphenyl

…, B Jakubowski, J Zawadiak

文献索引：Stec, Zbigniew; Orlinska, Beata; Jakubowski, BartLomiej; Zawadiak, Jan International Journal of Chemical Kinetics, 2008 , vol. 40, # 9 p. 527 - 532

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摘要

Abstract The kinetics of the oxidation of 4-isopropylbiphenyl (1) in the liquid phase by oxygen to 1-(1, 1′-biphenyl-4-yl)-1-methylethyl hydroperoxide (2) was investigated. The oxidizability of 1 in the temperature range from 60 C to 120 C and the overall energy activation of oxidation were determined. Long-term oxidation of 1 to 2 in the temperature range of 80–120 C was investigated, and the yield and selectivity of the process were ...