Electrohalogenation of propargyl acetates and amides to form the 1, 1-dibromo-2-oxo functionality and a facile synthesis of furaneol

T Inokuchi, S Matsumoto, M Tsuji…

文献索引：Inokuchi, Tsutomu; Matsumoto, Sigeaki; Tsuji, Michihiro; Torii, Sigeru Journal of Organic Chemistry, 1992 , vol. 57, # 18 p. 5023 - 5027

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被引用次数: 18

摘要

I Ich $ &- II I 2 a la OAc is inevitably required to facilitate the reaction. Consequently, finding a nonmercuric method of providing either 1, 2-diketones or synthetic equivalents is a desirable goal in current organic synthesis. Our attention was focused on halogenative hydroxylation processes involving acetylenic bonds, because a, a-dihalo ketones or their analogues are synthons of 1, Zdiketones which are versatile, highly functionalized intermediate^.^ To this ...