Synthesis and polymerization of a novel perfluorinated monomer

E Murotani, S Saito, M Sawaguchi, H Yamamoto…

文献索引：Murotani, Eisuke; Saito, Susumu; Sawaguchi, Masanori; Yamamoto, Hiromasa; Nakajima, Youji; Miyajima, Tatsuya; Okazoe, Takashi Journal of Fluorine Chemistry, 2007 , vol. 128, # 10 p. 1131 - 1136

全文：HTML全文

被引用次数: 6

摘要

Perfluoro (5-methylene-2, 2-dimethyl-1, 3-dioxolane)(1) was synthesized by utilizing a direct fluorination reaction. Compound 1 was an entirely novel monomer with difluoromethylene at position 5 on the dioxolane ring as an unprecedented polymerization site. It successfully polymerized with tetrafluoroethylene to afford copolymers, which had Tg values in the range of 60–90° C. The content of monomer 1 in the obtained polymers was less than 20mol%, ...