Selective Catalytic Hydrogenation of Heteroarenes with N-Graphene-Modified Cobalt Nanoparticles (Co3O4–Co/NGr@ α-Al2O3)

…, J Radnik, C Topf, K Junge, M Beller

文献索引：Jagadeesh, Rajenahally V.; Wienhoefer, Gerrit; Westerhaus, Felix A.; Surkus, Annette-Enrica; Pohl, Marga-Martina; Junge, Henrik; Junge, Kathrin; Beller, Matthias Chemical Communications, 2011 , vol. 47, # 39 p. 10972 - 10974

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被引用次数: 20

摘要

Cobalt oxide/cobalt-based nanoparticles featuring a core–shell structure and nitrogen- doped graphene layers on alumina are obtained by pyrolysis of Co (OAc) 2/phenanthroline. The resulting core–shell material (Co3O4–Co/NGr@ α-Al2O3) was successfully applied in the catalytic hydrogenation of a variety of N-heteroarenes including quinolines, acridines, benzo [h], and 1, 5-naphthyridine as well as unprotected indoles. The peculiar structure of ...