ACS catalysis

Copper-catalyzed carboxylation of aryl iodides with carbon dioxide

H Tran-Vu, O Daugulis

文献索引：Tran-Vu, Hung; Daugulis, Olafs ACS Catalysis, 2013 , vol. 3, # 10 p. 2417 - 2420

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被引用次数: 25

摘要

A method for carboxylation of aryl iodides with carbon dioxide has been developed. The reaction employs low loadings of copper iodide/N, N, N′, N′-tetramethylethylenediamine (TMEDA) or N, N′-dimethylethylenediamine (DMEDA) catalyst, 1 atm of CO2, dimethylsulfoxide (DMSO) or dimethylacetamide (DMA) solvent, and proceeds at 25–70° C. Good functional group tolerance is observed, with ester, bromide, chloride, fluoride, ether, ...