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Syntheses of the Three Isomeric Diethyl-and Dinepentyltetramethylbenzenes

MS Newman, JR LeBlanc, HA Karnes…

文献索引:Newman,M.S. et al. Journal of the American Chemical Society, 1964 , vol. 86, p. 868 - 872

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被引用次数: 29

摘要

The syntheses of the three isomeric diethyl-and dineopentyltetramethylbenzenes has been accomplished. Differences in the tendencies of the o-isomers as compared to the m-and p- isomers to complex with tetracyanoethylene and 2, 4, 7-trinitrofluorenone have been observed and briefly discussed. New syntheses of compounds containing cyclopropyl rings have been noted in the lithium aluminum hydride, sodium in liquid ammonia, and Raney ...