Designing polymers for biphasic liquid/liquid separations after homogeneous reactions

DE Bergbreiter, SD Sung, J Li, D Ortiz…

文献索引：Bergbreiter, David E.; Sung, Shayna D.; Li, Jun; Ortiz, Denisse; Hamilton, Patrick N. Organic Process Research and Development, 2004 , vol. 8, # 3 p. 461 - 468

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被引用次数: 37

摘要

The phase-selective solubility properties of polymer supports that could be used in thermomorphic and latent biphasic systems useful in synthesis and catalysis were evaluated using polymers tagged with either visible dyes or fluorescent probes. Heptane/DMF, heptane/90% ethanol-water, heptane/ethyl acetate, heptane/ethanol, and heptane/tert-butyl alcohol solvent mixtures were all studied as examples of thermomorphic or latent biphasic ...