Canadian journal of chemistry

Proton transfer reactions between ortho-methyl substituted derivatives of 4-nitrophenylphenylcyanomethane and nitrogen bases in acetonitrile solvent

KT Leffek, P Pruszynski

文献索引：Leffek, Kenneth T.; Pruszynski, Przemyslaw Canadian Journal of Chemistry, 1988 , vol. 66, p. 1454 - 1458

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被引用次数: 18

摘要

Equilibrium constants, rate constants, primary deuterium isotope effects, and activation parameters have been measured for the proton transfer reactions in acetonitrile solvent of 4- nitrophenylphenylcyanomethane and 2-methyl-4-nitrophenylphenyl-cyanomethane with tetramethylguanidine base and for the reactions of 2-methyl-4- nitrophenylphenylcyanomethane and 2, 6-di-methyl-4-nitrophenylphenylcyanomethane ...