Tetrahedron

Synthesis of aryltriethoxysilanes via rhodium (I)-catalyzed cross-coupling of aryl electrophiles with triethoxysilane

…, T Ueta, M Nagata, M Ishikura, S Watanabe, Y Masuda

文献索引：Murata, Miki; Yamasaki, Hiyoruki; Ueta, Tsukasa; Nagata, Masayuki; Ishikura, Masanori; Watanabe, Shinji; Masuda, Yuzuru Tetrahedron, 2007 , vol. 63, # 19 p. 4087 - 4094

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被引用次数: 36

摘要

The general and efficient silylation of aryl halides has been developed utilizing triethoxysilane and a rhodium catalyst. The substrate scope is broad and includes ortho-, meta-, and para-substituted electron-rich and-deficient aryl iodides. In addition, the silylation of aryl bromides and fluoroalkanesulfonates proceeded in the presence of tetra-n- butylammonium iodide.