Catalysis letters

Lanthanide Carboxylate Frameworks: Efficient Heterogeneous Catalytic System for Epoxidation of Olefins

R Sen, D Saha, S Koner

文献索引：Sen, Rupam; Saha, Debraj; Koner, Subratanath Catalysis Letters, 2012 , vol. 142, # 1 p. 124 - 130

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被引用次数: 20

摘要

Abstract Two lanthanide-based three dimensional metal–organic frameworks (MOF) viz.[Nd (HCOO) 3] n (1) and [Pr (HCOO) 3] n (2) have been synthesized and characterized. Both the compounds have similar structure. In this study we have demonstrated that the compounds are highly efficient in catalyzing epoxidation of various cyclic and linear olefinic substrates. MOF compounds are stable and recyclable under the reaction conditions. Notably, MOF ...