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Reductive Elimination of Ether from T??Shaped, Monomeric Arylpalladium Alkoxides

JP Stambuli, Z Weng, CD Incarvito…

文献索引:Stambuli, James P.; Weng, Zhiqiang; Incarvito, Christopher D.; Hartwig, John F. Angewandte Chemie - International Edition, 2007 , vol. 46, # 40 p. 7674 - 7677

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被引用次数: 37

摘要

Reductive elimination of ethers from organopalladium alkoxides is the C¿ O bond-forming step of the palladiumcatalyzed etherification of aryl halides.[1] At this time, examples of the reductive eliminations of ethers from isolated organopalladium alkoxide complexes are limited. Only reductive eliminations of alkyl aryl ethers from complexes generated in situ, reductive elimination of an oxygen heterocycle from a single oxapalladacycle,[2] reductive ...