Regioselectivity in the addition of vinylmagnesium bromide to heteroarylic ketones: C-versus O-alkylation

…, E Del Vecchio, L Forlani, PE Todesco

文献索引：Boga, Carla; Forlani, Luciano; Todesco, Paolo E. Gazzetta Chimica Italiana, 1997 , vol. 127, # 4 p. 197 - 200

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被引用次数: 21

摘要

The reactivity of heteroarylic ketones toward vinylmagnesium bromide (2) and the regiochemistry of the addition were investigated. The reactivity drastically increases when the carbonyl is conjugated with at least one aza group and the regiochemistry of the addition