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Folding and Aggregation of Cationic Oligo (aryl??triazole) s in Aqueous Solution

Y Wang, F Li, Y Han, F Wang…

文献索引:Wang, Ying; Li, Fei; Han, Yumiao; Wang, Fuyi; Jiang, Hua Chemistry - A European Journal, 2009 , vol. 15, # 37 p. 9424 - 9433

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被引用次数: 57

摘要

Abstract Cationic aryl triazole oligomers have been synthesized through “click chemistry”. The results show that cationic aryl triazole oligomers adopt a helical conformation in water or in a mixture of water and methanol, but prevail as a random-coiled conformation in methanol. Importantly, circular dichroism spectroscopy and dynamic light scattering experiments revealed that cationic oligomers aggregated intermolecularly to form higher ...