Evaluation of deep eutectic solvent–water binary mixtures for lipase-catalyzed lipophilization of phenolic acids

E Durand, J Lecomte, B Baréa, E Dubreucq, R Lortie…

文献索引：Durand, Erwann; Lecomte, Jerome; Barea, Bruno; Dubreucq, Eric; Lortie, Robert; Villeneuve, Pierre Green Chemistry, 2013 , vol. 15, # 8 p. 2275 - 2282

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被引用次数: 34

摘要

This work reports the first lipase-catalyzed reactions between substrates of different polarities using deep eutectic solvents as a medium. The model reaction consisted of a lipophilization process based on the alcoholysis of phenolic esters using immobilized Candida antarctica lipase B as a biocatalyst. Results showed that water could dramatically improve the lipase activity and change the reactivity of phenolic substrates. Indeed, very ...