Synthesis, Structural Characterization, and Thermoresponsivity of Hybrid Supramolecular Dendrimers Bearing a Polyoxometalate Core

H Chen, Y Yang, Y Wang, L Wu

文献索引：Chen, Hailong; Yang, Yang; Wang, Yizhan; Wu, Lixin Chemistry - A European Journal, 2013 , vol. 19, # 33 p. 11051 - 11061

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被引用次数: 0

摘要

Abstract A series of cationic dendrons bearing triethylene glycol monomethyl ether terminal groups of different generations have been synthesized and used to encapsulate an inorganic polyanionic cluster [K 12.5 Na 1.5 (NaP 5 W 30 O 110)] through electrostatic interactions. The resulting dendritic cation–encapsulated polyoxometalate (POM) complexes, cluster–dendrimers, are soluble in water and exhibit lower critical solution ...