Polarographic Studies in Acetonitrile and Dimethylformamide. IV. Stability of Anion-free Radicals1, 2

S Wawzonek, D Wearring

文献索引：Wawzonek; Wearring Journal of the American Chemical Society, 1959 , vol. 81, p. 2067

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被引用次数: 107

摘要

The polarographic reduction of stilbene, naphthalene, phenanthrene, biphenyl, a-terphenyl, m-terphenyl, diphenylacetylene and phenylacetylene in diinethylformarnide containing tetra- n-butylammonium iodide as a supporting elect1 olyte, has been carried out. The results point to the formation of monovalent anion-free radicals as intermediates in thc reduction of the first seven hydrocarbons. Substantiation for the mechanism of reduction was obtained ...