前往化源商城

Chemistry of cyclopropanols. VI. Cleavage by electrophilic halogen

CH DePuy, WC Arney Jr, D Gibson

文献索引:DePuy,C.H. et al. Journal of the American Chemical Society, 1968 , vol. 90, # 7 p. 1830 - 1840

全文:HTML全文

被引用次数: 29

摘要

Abstract: It has been shown that both &, trans-and truns, trans-2, 3-dimethyl-l- phenylcyclopropanols and their corresponding acetates react stereospecifically with a variety of brominating agents to form bromo ketones with complete insersion of configuration at the site to which the bromine becomes attached. Thus the &, trans isomer gives only erythro-a-methyl-P-bromobutyrophenone and the trans, truns isomer gives exclusively the ...