Synthetic Communications

Reaction of Chlorosulfonyl Isocyanate With 1, 2-Diols: Rearrangement and Formation of Carbonates

SP Joseph, DN Dhar

文献索引：Joseph, Sajan P.; Dhar, D. N. Synthetic Communications, 1988 , vol. 18, # 18 p. 2295 - 2302

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被引用次数: 7

摘要

The chemistry of 1,2-diols is well documented in 8 literature . Thus 1,2-diols are reported' to undergo ... The formation of the rearranged ketone can be ... The formation of the carbonates and hydroxy ... The epoxide formation is presumably by the attack ... The unsymmetrical diol, lk, gave two rearranged ... TABLE Yields of the products obtained from the reaction ... PMR spectrum (CDC13) 6 : 5.4 (s, 2H), 3.9-4.3 ... Mass Spectrum m/e (rel. int.): 159 (M'),