Tetrahedron

The preparation and reactions of primary phosphine oxides

SA Buckler, M Epstein

文献索引：Buckler,S.A.; Epstein,M. Tetrahedron, 1962 , vol. 18, p. 1221 - 1230

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被引用次数: 23

摘要

The preparation of primary phosphine oxides, RP (O) H2, by the controlled oxidation of primary phosphines is described. Some of the properties of these novel oxides are discussed and their reactions with olefins, carbonyl compounds and isocyanates are reported. These reactions lead to various types of symmetrical and unsymmetrical secondary and tertiary phosphine oxides. Polymers are obtained from reactions with a ...