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Journal of the American Chemical Society

Various Reactions of Organic Bases with 1, 1, 1-Trinitroethane and 1-Halo-1, 1-Dinitroethanes. 1, 1-Dinitroethene as a Reaction Intermediate1

L Zeldin, H Shechter

文献索引:Zeldin; Shechter Journal of the American Chemical Society, 1957 , vol. 79, p. 4708,4712

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被引用次数: 37

摘要

(3) To whom inquiries with respect to this research should be made.(4)(a) A. Hantzsch and A. Rinckenberger. Bcr., 51, 628 (1899).(b) This reaction is presumed to involve attack of the base on the positive nitrogen atom of a nitro group. An alternate possibility, though less attractive, involves displacement attack on oxygen of a nitro group to give the corresponding nitrito derivative. These two possible processes can not be differentiated from the results ...