Réactivité du 3, 3-bis (triméthylsilyl) propène vis-à-vis des ions iminium issus d'amines secondaires. Accès stéréosélectif à des (E)-β-aminovinylsilanes
B Princet, H Gardès-Gariglio, J Pornet
文献索引：Princet, Bruno; Gardes-Gariglio, Helene; Pornet, Jacques Journal of Organometallic Chemistry, 2000 , vol. 604, # 2 p. 186 - 190
The 3, 3-bis (trimethylsilyl) propene reacts with iminium ions generated in situ from secondary amines by an aminomethylation–desilylation process, leading to (E)-β- aminovinylsilanes. When a secondary amine with two secondary groups is used, the reaction fails, the steric hindrance probably inhibiting the reaction.
