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Branched triangulanes: general strategy of synthesis

NS Zefirov, SI Kozhushkov, BI Ugrak…

文献索引:Zefirov, Nikolai S.; Kozhushkov, Sergei I.; Ugrak, Bogdan I.; Lukin, Kirill A.; Kokoreva, Olga V.; et al. Journal of Organic Chemistry, 1992 , vol. 57, # 2 p. 701 - 708

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被引用次数: 31

摘要

A general synthetic strategy for the construction of branched triangulanes (BTs)(spirocondensed polycyclopropanes) has been elaborated. The synthetic utility of the method is illustrated by the synthesis of some members of the [5]-and [6] BT families, especially 13a, b and 14. An independent synthesis of the perspirocyclopropanated spiropentane 14 is also presented.