Sonolysis and photolysis are compared for the transformation of chlorpropham, a systemic herbicide belonging to the carbamate group, and 3-chloroaniline, the main intermediate often observed in the degradation of chlorpropham. In both cases the ultrasonic degradation is much more efficient at 482kHz than at 20kHz. The main identified sonoproducts formed in the degradation of chlorpropham are 3-chloroaniline, formic acid, carbon monoxide and ...