Abstract A preparative method for the synthesis of C-and N-difluoroaminooxy compounds was elaborated. The method involves the reaction of N, N-difluoro-O-fluorosulfonyl hydroxylamine with the corresponding alkoxides and N-oximide salts. It was shown that N- difluoroaminooxy compounds can add to olefins at the double bond.
![1,1,1,3,3,3-hexafluoro-2-[1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-yl]peroxy-2-(trifluoromethyl)propane结构式](https://image.chemsrc.com/caspic/426/26842-85-3.png)