Photolysis of cis??1, 2??dihydroxyindane carbonate and cw??1, 2??dihydroxy??1, 2, 3, 4??tetrahydronaphthalene carbonate

RC White, P Drew, R Moorman

文献索引：White, Rick C.; Drew, Phil; Moorman, Richard Journal of Heterocyclic Chemistry, 1988 , vol. 25, p. 1781 - 1783

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被引用次数: 10

摘要

Abstract Cyclic carbonate esters 2 and 3 were prepared and the photochemistry studied. The direct irradiation of these esters produces 1, 3-diradicals which undergo either ring closure to form epoxides, H migration to form ketones or Grob type fragmentation processes which lead to products via ring expansion or contraction.