Israel journal of chemistry

Thermal Isomerization of Azulene. Single??Pulse Shock Tube Investigation

A Laskin, A Lifshitz

文献索引：Laskin, Alexander; Lifshitz, Assa Israel Journal of Chemistry, 1996 , vol. 36, # 3 p. 257 - 261

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被引用次数: 7

摘要

Abstract The thermal isomerization of azulene was studied behind reflected shocks in a pressurized driver single-pulse shock tube. The temperature range covered was 1050–1400 K at overall densities of∼ 2.5× 10− 5 mol/cm 3. The main reaction of azulene under these conditions is a unimolecular isomerization to naphthalene, but it also isomerizes, although at a much lower rate, to another isomer. The suggested “tetracyclic triene” intermediate ...