Deoxygenation and Other Photochemical Reactions of Aromatic Selenoxides1

RD McCulla, WS Jenks

文献索引：McCulla, Ryan D.; Jenks, William S. Journal of the American Chemical Society, 2004 , vol. 126, # 49 p. 16058 - 16065

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被引用次数: 32

摘要

Atomic oxygen O (3P) is a potent oxidant that has been well-studied in the gas phase. However, exploration of its reactivity in the condensed organic phase has been hampered by the lack of an appropriate source. Dibenzothiophene-S-oxide (DBTO) and related derivatives have been promoted as photochemical O (3P) sources but suffer from low quantum yields. Photolysis of dibenzoselenophene-Se-oxide (DBSeO) results in the ...