High vibrational overtone photochemistry of 1-cyclopropylcyclobutene

JM Jasinski, JK Frisoli, CB Moore

文献索引：Jasinski, Joseph M.; Frisoli, Joan K.; Moore, C. Bradley Journal of Physical Chemistry, 1983 , vol. 87, p. 3826 - 3829

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被引用次数: 1

摘要

Laser excitation of high CH stretching overtones has been used to induce the isomerization of l-cyclopropylcyclobutene (CYCB) to 2-cyclopropyl-l, 3-butadiene. Values of the unimolecular isomerization rate constant, k (E), have been measured for excitation of the fifth cyclobutenyl and cyclopropyl methylenic CH stretching overtones. The values of k (E) depend only on total energy and do not show any identifiable dependence on which type ...