Journal of the American Chemical Society

An acetylenic analog of neopentyl bromide; evidence that the hindrance to displacement reactions in neopentyl halides is steric in nature

PD Bartlett, LJ Rosen

文献索引：Bartlett; Rosen Journal of the American Chemical Society, 1942 , vol. 64, p. 544

全文：HTML全文

被引用次数: 59

摘要

another atom or radical of similar (negative) ionic type. This is the class of reaction, variously “bimolecular nucleophilic substitution”(% 2), which at an optically active center is generally attended by Walden inversion, and which is accordingly believed to proceed by concerted attachment of the new substituent on one face of the krposed between the affecting and the carbon atom and release of the old one from the group.'Thus, the chemical effects of a ...