Journal of the American Chemical Society

Reactions of carboxylic acids in sulfuric acid

CM Welch, HA Smith

文献索引：Welch; Smith Journal of the American Chemical Society, 1953 , vol. 75, p. 1412,1414

被引用次数: 10

摘要

The reactions of several organic acids in sulfuric acid have been investigated. The" i" factors have been determined by cryoscopic methods, the evolution of carbon monoxide studied, and the carbonium ions present when the acids are dissolved in sulfuric acid have been allowcd to react with various reagents. The influence of certain substituents on the stability of the carbonium ions also has been investigated. 4 n interesting and peculiar preparation of ...

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