Tetrahedron

The synthesis of 12-fluoro-7-methyl-and 7-fluoro-benz [a] anthracene: A contribution to the study of photocyclization

J Blum, F Grauer, ED Bergmann

文献索引：Blum,J. et al. Tetrahedron, 1969 , vol. 25, p. 3501 - 3507

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被引用次数: 10

摘要

In order to study the influence of fluorine substitution at the meso-position of benz [a] anthracene and at the 12-position of 7-methylbenz [a] anthracene on the carcinogenic properties of these hydrocarbons, the title compounds have been prepared by photocyclization of 1-(1-f1uoro-2-naphthyl)-2-(o-iodophenyl) ethylene and 1-(4-fluoro-1- methyl-2-naphthyl)-2-(o-iodophenyl) ethylene, respectively.