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The Journal of organic chemistry

Scope and limitations of the Pd/BINAP-catalyzed amination of aryl bromides

JP Wolfe, SL Buchwald

文献索引:Itier,J.; Casadevall,A. Bulletin de la Societe Chimique de France, 1969 , p. 2342 - 2355

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被引用次数: 477

摘要

... weak bases such as alkali metal carbonates and phosphates, 2e,j as well as organic bases such as tertiary amines and DBU. These generally gave poorer results in the amination reactions. The activated substrate 4-bromobenzonitrile was efficiently coupled with p-toluidine in ...