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Two approaches to the synthesis of 9-oxo-and 10-hydroxy-2E-decenoic acids, important components of queen substance and royal jelly of honeybees Apis mellifera

GY Ishmuratov, MP Yakovleva, KA Tambovtsev…

文献索引:Ishmuratov; Yakovleva; Tambovtsev; Legostaeva; Kravchenko; Ishmuratova; Tolstikov Chemistry of Natural Compounds, 2008 , vol. 44, # 1 p. 74 - 76

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被引用次数: 6

摘要

Abstract Two approaches to the synthesis of 9-oxo-and 10-hydroxy-2 E-decenoic acids, biologically active components of queen substance and royal jelly of honeybees, respectively, were proposed starting with allyl bromide and 1, 7-octadiene and using chemo- and regioselective transformations of the common intermediate building block 7-octen-1- ylacetate.