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Journal of the American Chemical Society

8-R-thio-and 8-R-sulfonylcaffeine derivatives

LM Long

文献索引:Long Journal of the American Chemical Society, 1947 , vol. 69, p. 2939

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被引用次数: 9

摘要

Summary Methyl y-(6-methoxy-1, 2, 3, 4-tetrahydro-1-naphthy1idene)-crotonate has been prepared by the reaction of 6-methoxy-a-tetralone and methyl y-bromocrotonate in the presence of zinc. This compound was isomerized to methyl y-(G-methoxy-1-naphthyl)- butyrate by heating with palladium-charcoal. The acid obtained from that compound on hydrolysis was cyclized with hydrogen fluoride to the equilenin intermediate l-keto-7- ...