Titanium (IV) tert-butoxide-tert-butyl hydroperoxide system as oxidant for CH bonds in hydrocarbons and oxygen-containing compounds

LP Stepovik, MV Gulenova, IM Martynova

文献索引：Stepovik; Gulenova; Martynova Russian Journal of General Chemistry, 2005 , vol. 75, # 4 p. 507 - 513

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被引用次数: 8

摘要

Abstract The system Ti (IV) tetra-tert-butoxide-tert-butyl hydroperoxide in mild conditions (20° C) oxidizes CH bonds of methyl (toluene), methylene (hexane, ethylbenzene, benzyl ethyl ether), and methine (1, 1-diphenylethane, triphenylmethane) groups. The role of oxidant is played by the oxygen generated by the system. The process involves free radicals and produces hydroperoxides and Ti (IV) peroxides. The latter decompose both with ...